[PDF.39nz] Ab Initio Calculations of Conformational Effects on 13C NMR Spectra of Amorphous Polymers (NMR Basic Principles and Progress)

Ab Initio Calculations of Conformational Effects on 13C NMR Spectra of Amorphous Polymers (NMR Basic Principles and Progress)

[PDF.as48] Ab Initio Calculations of Conformational Effects on 13C NMR Spectra of Amorphous Polymers (NMR Basic Principles and Progress)

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 |  Springer |  2011-09-16 | Original language:Delaware | PDF # 1 |  9.25 x.32 x6.10l,.45 | File type: PDF | 126 pages

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In NMR, it is well-known that the chemical shift conveys structural informa­ tion, e. g. a carbonyl carbon will have a resonance frequency appreciably dif­ ferent from a methyl carbon, etc. The relation between structure and chemical shift is mostly established by empirical rules on the basis of prior experience. It is only quite recently that the advent of both comparatively cheap comput­ ing power and novel quantum chemistry approaches have provided feasibl...

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