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Deuterium and Shift Calculation (NMR Basic Principles and Progress)

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 |  Springer |  2012-02-24 | Original language:English | PDF # 1 |  9.25 x.63 x6.10l,.86 | File type: PDF | 263 pages

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In 1931 Vrey, Brickwedde, and Murphy discovered the hydrogen isotope deuterium. The isotopic enrichment was found to arise from the fact that the electrolysis oflight water is faster than of heavy water [1,2]. This success showed that although different isotopes of an element behave identically from a chemical standpoint the different isotopic masses nevertheless lead to both isotope effects on equilibrium as well as on rate constants of chemical reactions. Soon, ratios ...

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