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The Chemistry of Zirconacycles and 2,6-Diazasemibullvalenes: Synthesis, Structures, Reactions, and Applications in the Synthesis of Novel N-Heterocycles (Springer Theses)

Shaoguang Zhang




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 |  Zhang Shaoguang |  2016-08-23 |  2016-08-23 | Original language:English | PDF # 1 |  9.25 x.45 x6.10l,.60 | File type: PDF | 173 pages

 | The Chemistry of Zirconacycles and 2 6 Diazasemibullvalenes Synthesis Structures Reactions and Applications in the Synthesis of Novel N Heterocycles

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In this thesis, the author introduces two strategies used to construct various types of N-heterocycles, based on the chemistry of zirconacycles and 2,6-diazasemibullvalenes. In the first part, the author presents the development of multi-component cyclization of a zirconacyclobutene-silacyclobutene fused compound, nitriles and unsaturated compounds. These reactions provide synthetically useful methodology for various N-heterocycles such as 3-acyl pyrrole, pyrrolo[3,2-...

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